Lesson 2.4 · 2. Quantum Mechanics

Entanglement & Measurement

Entanglement is perhaps the strangest feature of quantum mechanics, what Einstein called "spooky action at a distance." Two particles can be correlated in ways that have no classical explanation, and these correlations persist regardless of how far apart the particles travel.

Composite Systems

When we have two quantum systems, the combined state space is the tensor product of the individual spaces.

What is a tensor product?

The tensor product $\otimes$ is a way of combining two separate state spaces into a single, larger space that describes both systems together. If system A can be in 2 states and system B can be in 3 states, the combined system has $2 \times 3 = 6$ possible basis states. The tensor product captures all possible combinations of the individual states.

Tensor Products

If system A has states $|a_1\rangle, |a_2\rangle, \ldots$ and system B has states $|b_1\rangle, |b_2\rangle, \ldots$, the combined system has states:

$$|a_i\rangle \otimes |b_j\rangle = |a_i, b_j\rangle = |a_i b_j\rangle$$

Reminder: superposition

Superposition means a quantum system can exist in a combination of multiple states at once. The system is not in one state or another, but genuinely in all of them simultaneously, with coefficients $c_{ij}$ that determine the probability of each outcome when a measurement is made.

A general state is a superposition:

$$|\Psi\rangle = \sum_{i,j} c_{ij} |a_i\rangle \otimes |b_j\rangle$$

Product States vs. Entangled States

A product state (or separable state) can be factored:

$$|\Psi\rangle = |\phi\rangle_A \otimes |\chi\rangle_B$$

An entangled state cannot be written as a product. The subsystems do not have independent states.

What is a qubit?

A qubit (quantum bit) is the quantum version of a classical bit. A classical bit is either 0 or 1; a qubit can be in a superposition of both. The simplest physical example is a particle's spin, which can be "up" $|\uparrow\rangle$, "down" $|\downarrow\rangle$, or any quantum combination of the two.

Example: Two Qubits

Product state: $|\uparrow\rangle|\downarrow\rangle$, first spin is up, second is down

Entangled state: $\frac{1}{\sqrt{2}}(|\uparrow\downarrow\rangle + |\downarrow\uparrow\rangle)$, cannot be factored!

The Bell States

The maximally entangled states of two qubits. They form a complete basis for the two-qubit space.

Bell Basis

$$|\Phi^+\rangle = \frac{1}{\sqrt{2}}(|\uparrow\uparrow\rangle + |\downarrow\downarrow\rangle)$$ $$|\Phi^-\rangle = \frac{1}{\sqrt{2}}(|\uparrow\uparrow\rangle - |\downarrow\downarrow\rangle)$$ $$|\Psi^+\rangle = \frac{1}{\sqrt{2}}(|\uparrow\downarrow\rangle + |\downarrow\uparrow\rangle)$$ $$|\Psi^-\rangle = \frac{1}{\sqrt{2}}(|\uparrow\downarrow\rangle - |\downarrow\uparrow\rangle)$$
S A B entangled |Ψ⁻⟩ = (|↑↓⟩ - |↓↑⟩)/√2
An entangled pair: measuring one instantly determines the other

Perfect Correlations

Consider $|\Psi^-\rangle$: if you measure particle A and find spin up, particle B is instantly spin down, no matter how far apart they are. The outcomes are perfectly anti-correlated.

But here's the twist: before measurement, neither particle has a definite spin. The correlation exists without predetermined values.

The EPR Paradox

In 1935, Einstein, Podolsky, and Rosen argued that quantum mechanics must be incomplete.

The Argument

EPR defined a criterion for physical reality: if we can predict a property with certainty without disturbing the system, that property is "real."

For an entangled pair:

  1. Measure spin-z on particle A → we know B's spin-z with certainty
  2. Alternatively, measure spin-x on A → we know B's spin-x with certainty
  3. These measurements on A don't disturb B (locality assumption)
  4. Therefore, B "really" has both spin-z and spin-x values
  5. But quantum mechanics says B can't have definite values for both simultaneously!

EPR concluded: quantum mechanics is incomplete. There must be "hidden variables" determining the outcomes.

Einstein's View

"God does not play dice." Einstein believed the apparent randomness reflected our ignorance, not fundamental indeterminacy. The correlations should arise from shared information carried by the particles from their common origin.

Bell's Theorem

In 1964, John Bell showed that the debate could be settled experimentally. Local hidden variable theories make predictions that differ from quantum mechanics.

The Setup

Two particles fly apart. Each reaches a detector that can be set to measure spin along one of several directions. The measurement outcomes are +1 or -1.

Setting a Setting b Result: A = ±1 Result: B = ±1
Bell experiment: detectors at different angles test quantum vs. classical correlations

The Bell Inequality (CHSH form)

What are hidden variables?

Hidden variables are hypothetical pre-existing properties that particles carry with them, determining measurement outcomes in advance. The idea is that quantum randomness might just reflect our ignorance of these hidden properties, much like a coin flip seems random only because we do not track the exact forces involved. Bell's theorem tests whether such hidden properties can explain all quantum predictions.

What is a correlation function?

A correlation function $E(a,b)$ measures how strongly two measurement outcomes are related. If the outcomes always match, $E = +1$; if they always oppose, $E = -1$; if they are unrelated, $E = 0$. By comparing correlations at different detector settings, we can distinguish quantum predictions from classical ones.

Define the correlation function $E(a,b)$ as the average product of outcomes when A uses setting $a$ and B uses setting $b$.

For any local hidden variable theory:

CHSH Inequality

$$|E(a,b) - E(a,b') + E(a',b) + E(a',b')| \leq 2$$

This is a mathematical constraint on any theory where outcomes are determined by local hidden variables.

Quantum Mechanics Violates the Inequality

For the singlet state $|\Psi^-\rangle$ with optimal angle choices:

$$|E(a,b) - E(a,b') + E(a',b) + E(a',b')| = 2\sqrt{2} \approx 2.83$$

Quantum mechanics predicts a value exceeding 2. Experiments consistently confirm the quantum prediction.

What Bell's Theorem Proves

No local hidden variable theory can reproduce all predictions of quantum mechanics. Either:

  • Locality fails: Measuring A instantly affects B (but no faster-than-light signaling is possible)
  • Realism fails: Particles don't have definite properties before measurement

Most physicists accept some form of nonlocality, while noting that it cannot be used for faster-than-light communication.

The Measurement Problem

Unitary evolution and eigenstates

"Unitary" means the evolution preserves total probability (nothing is gained or lost) and is reversible, like a smoothly rotating dial that can always be turned back. An "eigenstate" of a measurement is a state with a definite value for that measurement. When a system is measured, it jumps to one of these eigenstates, and the measured value is the corresponding eigenvalue.

Quantum mechanics describes two types of evolution:

  1. Unitary evolution: The Schrödinger equation evolves states smoothly and deterministically
  2. Measurement: The state "collapses" to an eigenstate, probabilistically

But what exactly constitutes a "measurement"? When does collapse happen? This is the measurement problem.

Schrödinger's Cat

Schrödinger's famous thought experiment highlights the problem. A cat in a box is entangled with a radioactive atom:

$$|\Psi\rangle = \frac{1}{\sqrt{2}}(|\text{undecayed}\rangle|\text{alive}\rangle + |\text{decayed}\rangle|\text{dead}\rangle)$$

Before we look, is the cat in a superposition of alive and dead? When does the superposition resolve?

atom detector amplifier observer (brain?) Where does collapse happen?
The measurement chain: at what point does "measurement" occur?

Different interpretations give different answers to this question (see next lesson).

Decoherence

Decoherence explains why we don't see quantum superpositions in everyday life, though it doesn't fully solve the measurement problem.

The Mechanism

Real systems interact with their environment: air molecules, photons, stray electromagnetic fields. These interactions cause entanglement with the environment:

$$|\psi\rangle|E_0\rangle \to \alpha|a\rangle|E_a\rangle + \beta|b\rangle|E_b\rangle$$

When the environment states $|E_a\rangle$ and $|E_b\rangle$ become orthogonal, interference between $|a\rangle$ and $|b\rangle$ vanishes, for any practical observation of the system alone.

The Density Matrix

What is a density matrix?

The density matrix $\rho$ is a more general way to describe quantum states than a wavefunction. It can represent both "pure" states (where we have complete quantum information, like a single definite wavefunction) and "mixed" states (where there is genuine classical uncertainty about which state the system is in, like a coin that is heads or tails but we have not looked). It is essential when dealing with systems that interact with their environment.

Tracing over and reduced density matrix

"Tracing over" the environment means mathematically summing out all the environmental degrees of freedom that we cannot observe. The result is the "reduced" density matrix for the system alone. It is like averaging over everything you cannot see in order to describe only the part you can access.

Tracing over the environment, the system's reduced density matrix evolves from pure to mixed:

$$\rho = |\alpha|^2|a\rangle\langle a| + |\beta|^2|b\rangle\langle b|$$

This looks like a classical probability distribution. The off-diagonal "coherence" terms (the entries that encode quantum interference between $|a\rangle$ and $|b\rangle$) have decayed away, leaving only classical probabilities on the diagonal.

What Decoherence Explains

  • Why cats appear either alive or dead, not in superposition
  • Why classical behavior emerges at macroscopic scales
  • The preferred "pointer" basis of measurement outcomes
  • The emergence of classical probability from quantum amplitudes

What Decoherence Doesn't Explain

  • Why we see a particular outcome rather than others
  • Where the other branches "go" (if anywhere)

Decoherence Timescales

Decoherence is extremely fast for macroscopic objects:

System Decoherence time
Large molecule in air ~10⁻³¹ seconds
Dust grain ~10⁻³⁶ seconds
Cat ~10⁻⁴² seconds
Superconducting qubit (engineered isolation) ~10⁻⁶ seconds

This explains why quantum effects are hard to observe macroscopically. Any superposition decoheres almost instantly.

Quantum Information

Entanglement isn't just a philosophical curiosity. It's a resource for information processing.

Quantum Teleportation

The no-cloning theorem

Quantum mechanics forbids making an exact copy of an unknown quantum state. This is fundamentally different from classical information, which can be copied freely. The no-cloning theorem is what makes quantum teleportation interesting: the original state must be destroyed in the process of transmitting it, so information is transferred, not duplicated.

Using a shared entangled pair plus classical communication, one can transmit a quantum state without physically sending the particle. The original state is destroyed in the process.

Quantum Cryptography

Entanglement enables fundamentally secure key distribution. Any eavesdropping disturbs the entangled state, revealing the intruder.

Quantum Computing

Entanglement provides computational power beyond classical computers. An $n$-qubit register can exist in a superposition of $2^n$ states, with entanglement correlating them in useful ways.

Key Takeaways
  • Entanglement is a purely quantum correlation with no classical analog
  • Entangled particles don't have independent states. The whole has properties the parts don't
  • Bell's theorem rules out local hidden variable explanations of quantum correlations
  • Experiments confirm quantum mechanics: nature is nonlocal in some sense
  • The measurement problem remains open: when and how does collapse happen?
  • Decoherence explains the emergence of classical behavior but doesn't fully solve measurement
  • Entanglement is a resource for quantum information processing